XML

Here is an XML file named "countries.xml":

<?xml version="1.0" encoding="ISO-8859-1"?>

<countries>

<country>
  <text>Norway</text>
  <value>N</value>
</country>

<country>
  <text>Sweden</text>
  <value>S</value>
</country>

<country>
  <text>France</text>
  <value>F</value>
</country>

<country>
  <text>Italy</text>
  <value>I</value>
</country>

</countries>

<%@ Import Namespace="System.Data" %>

Next, create a DataSet for the XML file and load the XML file into the DataSet when the page is first loaded:
<script runat="server">
sub Page_Load
if Not Page.IsPostBack then
  dim mycountries=New DataSet
  mycountries.ReadXml(MapPath("countries.xml"))
end if
end sub
To bind the DataSet to a RadioButtonList control, first create a RadioButtonList control (without any asp:ListItem elements) in an .aspx page:
<html>
<body>

<form runat="server">
<asp:RadioButtonList id="rb" runat="server" AutoPostBack="True" />
</form>

</body>
</html>
Then add the script that builds the XML DataSet:
<%@ Import Namespace="System.Data" %>

<script runat="server">
sub Page_Load
if Not Page.IsPostBack then
  dim mycountries=New DataSet
  mycountries.ReadXml(MapPath("countries.xml"))
  rb.DataSource=mycountries
  rb.DataValueField="value"
  rb.DataTextField="text"
  rb.DataBind()
end if
end sub
</script>

<html>
<body>

<form runat="server">
<asp:RadioButtonList id="rb" runat="server"
AutoPostBack="True" onSelectedIndexChanged="displayMessage" />
</form>

</body>
</html>
Then we add a sub routine to be executed when the user clicks on an item in the RadioButtonList control. When a radio button is clicked, a text will appear in a label:

Example

<%@ Import Namespace="System.Data" %>

<script runat="server">
sub Page_Load
if Not Page.IsPostBack then
  dim mycountries=New DataSet
  mycountries.ReadXml(MapPath("countries.xml"))
  rb.DataSource=mycountries
  rb.DataValueField="value"
  rb.DataTextField="text"
  rb.DataBind()
end if
end sub

sub displayMessage(s as Object,e As EventArgs)
lbl1.text="Your favorite country is: " & rb.SelectedItem.Text
end sub
</script>

<html>
<body>

<form runat="server">
<asp:RadioButtonList id="rb" runat="server"
AutoPostBack="True" onSelectedIndexChanged="displayMessage" />
<p><asp:label id="lbl1" runat="server" /></p>
</form>

</body>
</html>